There is no Username/Password authentication endpoint registered with the Microsoft Office 365 authentication system.
\Admin_Applications\SSO_Diagnostic_Tests\ADFSDiagnostic.txt
In addition, you may notice one of the following symptoms when you sign in to Office 365 resources by using single sign-on (SSO)-enabled user ID credentials:- Rich client applications authentication fails when you are trying to access services remotely from an Internet-connected client computer.
- Authentication for Exchange Online client applications fails when you connect to resources.