For more information about how to assign the drive letter during the deployment of the operating systems, click the following article numbers to view the articles in the Microsoft Knowledge Base:
307844
How to change drive letter assignments in Windows XP
300415 A description of the Diskpart command-line utility
Windows operating systems typically cannot modify the drive letters that are assigned to the system drive or to the boot drive.
For more information about how to change the drive letter that is assigned to the system drive or to the boot drive, click the following article numbers to view the articles in the Microsoft Knowledge Base:
223188
How to restore the system/boot drive letter in Windows
830577 How to set the drive letter for the system drive when you install Microsoft Windows Server 2003