The following workaround exist for this issue:
1. For customers that have the Hotfix Rollup 5 applied (Build # 5.0.1500.2985), apply the KB # 2405516. This KB is required to fix a critical bug of the NF-e feature.
NOTE: KB # 2405516 refers to the Hotfix Rollup 6 and is an essential part of the described workaround.
2. Go to the Basic Module, click Setup, click Brazil, click Brazilian Parameters.
3. Apply the addresses of the Web Services from São Paulo State for each kind of Web Service and click the Generate button.
4. Change the address of the Web Services from São Paulo State to the State in which the customer is located, do not click the Generate button, just save the changes.