The Remote Assistance session is unable to start because the Expert is unable to obtain a Kerberos ticket to the computer or user account of the Novice.
This can occur after the Windows Server 2003 domain krbtgt account has been authoritatively restored and the version of the password for the krbtgt account has been increased during the restore to be greater than 255.
When an Expert attempts to offer unsolicited Remote Assistance from Windows 7, the computer first tries to obtain a Kerberos ticket for the user account on the Novice's computer. Since no service principal name (SPN) is registered on the user account, the Kerberos Key Distribution Center (KDC) service on the domain controller returns the error KDC_S_PRINCIPAL_UNKNOWN and falls back to User2User authentication. The expert gets the novice user’s ticket granting ticket (TGT) which was emitted by the Windows Server 2003 domain controller and inspects it to know if the request should be sent to the KDC or a read-only domain controller (RODC). Since the version of the krbtgt password is higher than 255, the Expert computer mistakenly attempts to find a RODC, which fails.